%%EOF These developments help to increase yields, reduce the energy consumption and other running costs and reduce the capital expenditure of new plants as well as enabling plant de-bottlenecks and revamps.

After plant start-up, Shell Catalysts & Technologies will continue to provide operational support. 450 0 obj<>stream RELIANCE ON ANY INFORMATION SUPPLIED IN THIS PUBLICATION IS SOLELY AT YOUR OWN RISK. �š��&2�ĵ���Y�>)��~Y�?��� �-�"��Q�iR�g3h o1�j!0�����HQU��9CxE�'[#�zs���I�F��ڬ. ASTs have a…, Presented here are equations governing heat transfer in a moving-bed heat exchanger, along with a numerical method for solving them…, The following titles are recently published books of potential interest to various parts of the chemical process industries (CPI) Human…, A heightening interest in 'green' hydrogen, A novel, structural, carbon-negative cement, New investment announced in platform technology for bio-based monomers, Acetylene-selective MOFs for ethylene purification, A fast-acting, durable self-disinfecting polymer, Nanoparticles improve lubricant performance in friction and wear prevention, First full integration of hydrogen production, distribution, storage and use is underway, A microwave-plasma process that efficiently makes hydrogen and acetylene, Airset regulators for On/Off Valve Applications, Design of Bulk-Solids Moving-Bed Heat Exchangers, Facts At Your Fingertips: Roof Classifications of Atmospheric Storage Tanks, Propionic Acid Production from Propionaldehyde, Mitigate Dust Hazards With Good Equipment and System Design, Integrated, virtualized capital-project execution lowers costs, New solid lubricant reduces static and friction, An integrated IoT software for water-treatment facilities, New 80-GHz compact radar transmitters for level, A non-metallic, curved-top motor-disconnect switch, Service and support expanded with this new portal, Comprehensive connectivity and monitoring for heat-trace systems, Gear units designed for food-processing drive systems, Industry’s first ‘four-in-one’ compact flowmeter, On-site N2 supplied by these membrane-based systems, An efficient dust collector with a small footprint, Evaporators: Energy Conservation Strategies and Process Control, Facts At Your Fingertips: Hopper Outlet Geometry and Arching, CE Voices: PNNL's Chemical Transformations Initiative, Technology Profile: Production of Orthophthalic Unsaturated Polyester, Recently Published Books for November 2020, Process Engineer - EDL Energy - East Lansing, MI, Assistant Professor in Computer Engineering - University of Texas Rio Grande Valley - Rio Grande Valley, TX, Third Class Engineer Power Plant - Crane Currency - Dalton, MA, Process Engineer - STEMCO - Millington, MI, Sr. to manufacture ethylene glycols varies widely between regions: North America (66%), western Europe (43%), Japan (68%) and the Middle East (99%) (Lacson, 2003).
Editor’s Note: The content for this column is supplied by Intratec Solutions LLC (Houston; www.intratec.us) and edited by Chemical Engineering. The first step in the production of ethylene is to take the feedstock and crack it into ethylene and other various products in a furnace. Mono-ethylene glycol (MEG) is an important raw material having numerous research and industrial applications, ... during recovery, typically during the early production stages when the produced water contains just low amounts of dissolved salts (Bikkina et al.

trailer << /Size 76 /Info 60 0 R /Root 63 0 R /Prev 128368 /ID[<14e1516fef0ce1f416fd0c8e20f6dc8c><0f407fb9c3f345114054c09d31f71423>] >> startxref 0 %%EOF 63 0 obj << /Type /Catalog /Pages 59 0 R /Metadata 61 0 R >> endobj 74 0 obj << /S 70 /Filter /FlateDecode /Length 75 0 R >> stream In the described process, MEG is produced via EO, which is manufactured in an integrated plant utilizing Shell EO technology. ETHYLENE OXIDE AND ETHYLENE GLYCOL (January 1997) Ethylene oxide (EO) and ethylene glycol (EG) are widely used industrial organic intermedi-ates. The two primary feedstocks for ethylene production are naphtha and natural gas (ethane, propane, butane, etc.). It can…, This column is based on “Propionic Acid Production from Propionaldehyde – Cost Analysis,” a report published by Intratec.

Figure 1 depicts MEG production from ethylene via a process similar to the OMEGA catalytic process from Shell Global Solutions (The Hague, the Netherlands; www.shell.com). 0000000016 00000 n Industrial Lubricants and Oils for Business, New Energies: building a lower-carbon power business, Sustainability reporting and performance data, Shell Rimula Truck & Heavy-duty Engine Oils, More and cleaner energy solutions for your business, Our home energy offer for households in Great Britain, Shell invoicing channels and invoice requirements, Purchase order general terms and conditions, Electronic signature data privacy statement, Shell Ariba Procurement: Transforming Shell’s supply chains, Health, Security, Safety and the Environment, Subscribe to Shell Catalysts & Technologies, View Industrial Lubricants and Oils for Business, Flightpath: Exploring the Future of Aviation, The benefits of chemicals in everyday life, Shell FuelSave Diesel and Shell Diesel Extra, Shell Fuel Oil Plus and Shell Fuel Oil Extra, Shell Electronic Vendor Managed Inventory, HSSE & Social Performance Commitment and Policy. 0000002203 00000 n © 2020 Access Intelligence, LLC. 0000004447 00000 n �8. Ethylene oxide production. PDF startxref The resulting EO stream is directed to the next section. EC is produced from EO using a phosphonium halide catalyst The overall result of the two- step process is that MEG yield in ethylene glycols product is extremely high (99–99.5%). Already a Chemical Engineering gold or platinum member? 19 0 obj <> endobj

MEG is conventionally produced through the hydrolysis of ethylene oxide (EO), which itself is obtained via ethylene oxidation. Shell Catalysts & Technologies is dedicated to delivering catalyst products and licensing solutions that provide value to your entire enterprise. ؚ=�X9�S[�Y��wa����ȳ8�����5I��]�y�Mub��͖��M�p�G�� ��b՜D�ұ����1-z����V6-@��z�C�j6�T�a&���ȭ�OaS�Q�2�Q0~84��|\�b.��=p =�Z�l�f��[�� ���^���Tk���,YF�s���4ܥ]5K��-�� �;�z��M�����;���)������v���ӓ'"�;QP�T�[� `�"(O�i�Hdw��ܝ/�žE�q��

This exothermic reaction, conducted in fixed beds in the reactor tubes, occurs in the gaseous phase with the use of a silver catalyst supported on alumina. �����~]}}���{3[D�E��W�I�ا�}Z���g�����on]�\FE�e�g�|������v��+�/�(a�8w�����}܉��R�J�=[U�S��z�';�[��8(mX��ѤQ�r��v~����|Z}Y��~{�bo��g㣏��x��d�[&Q��ut��������e�|x�CYQQ�Y�G���&�-�d�C3�S#:�ԓ�{�]��0��L�7��T��^}�WZ�#>mNl�E�dW@X�)�㝬��݊Z�\hIBA��dL*+} Y��.nD��:Jjq��^H�Z�Ce��أj�V�L��;�����Vu;�Ɍ:�d>FP᭬x�#z��u�"C�s¿:i��7�b���%Ux>.K/���~SD���q�Y(?H���ͪRCgz�U�� In this unit, CO2 is separated to be used in ethylene carbonate production. <]>> 0000007423 00000 n According to the licenser, the process is able to achieve EO-to-EG converstion and selectivity near 100%, leading to production of MEG only. The content represents the opinions of Intratec only. Shell innovations in 1971 increased catalyst selectivity to 80% which was interpreted to be its theoretical limits by industry experts. 0 The first step in the production of ethylene is to take the feedstock and crack it into ethylene and other various products in a … MEG is purified in two distillation columns where water is removed, leading to the final MEG product. This publication contains text, graphics, images, and other content (collectively "Content"), which are for informational purposes only.

Ethylene glycol used to be manufactured by the hydrolysis of ethylene oxide (EO) which was produced via ethylene chlorohydrin but this method has been superseded by a direct oxidation route. Contact Shell Catalysts & Technologies to meet the challenges petrochemical plants face with confidence.

Privacy Policy. In general, an environmentally friendly process with low carbon emissions and waste is … H�b```a``�"��� �fb����P�"FW�< �M̸иP@��b<��N~:k�00p30 �K� endstream endobj 75 0 obj 82 endobj 64 0 obj << /Type /Page /Parent 59 0 R /Resources << /Font << /F0 65 0 R /F1 70 0 R /F2 68 0 R >> /ProcSet 73 0 R >> /Contents 71 0 R /MediaBox [ 0 0 612 792 ] /CropBox [ 0 0 612 792 ] /Rotate 0 >> endobj 65 0 obj << /Type /Font /Subtype /TrueType /Name /F0 /BaseFont /Swis721BT,Bold /FirstChar 32 /LastChar 255 /Widths [ 285 333 333 761 571 857 690 166 380 380 500 833 285 333 285 309 571 571 571 571 571 571 571 571 571 571 309 309 833 833 833 547 1000 690 714 738 738 642 595 785 738 309 547 714 571 880 738 785 666 785 714 666 595 714 619 928 619 619 595 380 309 380 1000 500 500 571 619 547 619 571 333 619 595 261 261 547 285 880 595 619 619 619 380 547 309 595 523 761 523 547 500 500 500 500 833 595 595 595 833 833 833 833 833 833 833 833 833 833 833 595 595 595 595 833 833 833 833 833 833 833 833 833 833 833 833 595 595 833 285 333 571 571 166 595 595 500 500 833 428 452 833 333 833 547 333 833 833 380 500 619 500 500 500 833 452 452 380 380 880 547 571 642 1285 690 690 690 1000 738 642 642 690 690 309 642 309 309 500 738 785 309 785 690 785 619 785 714 785 785 714 738 619 595 571 571 571 571 571 571 880 547 571 571 571 571 261 261 261 261 500 595 619 619 619 619 619 261 619 595 595 595 595 619 547 500 ] /Encoding /WinAnsiEncoding /FontDescriptor 66 0 R >> endobj 66 0 obj << /Type /FontDescriptor /FontName /Swis721BT,Bold /Flags 16416 /FontBBox [ -250 -236 1543 1162 ] /MissingWidth 381 /StemV 151 /StemH 151 /ItalicAngle 0 /CapHeight 963 /XHeight 482 /Ascent 963 /Descent -236 /Leading 199 /MaxWidth 1286 /AvgWidth 476 >> endobj 67 0 obj << /Type /FontDescriptor /FontName /Arial,Bold /Flags 16416 /FontBBox [ -250 -212 1200 1055 ] /MissingWidth 333 /StemV 153 /StemH 153 /ItalicAngle 0 /CapHeight 905 /XHeight 453 /Ascent 905 /Descent -212 /Leading 150 /MaxWidth 1000 /AvgWidth 479 >> endobj 68 0 obj << /Type /Font /Subtype /TrueType /Name /F2 /BaseFont /Arial /FirstChar 32 /LastChar 255 /Widths [ 285 333 357 547 547 880 666 190 333 333 380 595 285 333 285 285 547 547 547 547 547 547 547 547 547 547 285 285 595 595 595 547 1023 666 666 714 714 666 619 785 714 285 500 666 547 833 714 785 666 785 714 666 619 714 666 1000 642 666 619 285 285 285 452 547 333 547 547 500 547 547 309 547 547 238 238 500 238 857 547 547 547 547 333 476 285 547 547 690 523 500 500 333 261 333 595 761 761 761 595 595 595 595 595 595 595 595 595 595 595 761 761 761 761 595 595 595 595 595 595 595 595 595 595 595 595 761 761 595 285 333 547 547 547 547 261 547 333 738 380 547 595 333 738 547 404 547 333 333 333 571 547 285 333 333 357 547 833 833 833 619 666 666 666 666 666 666 1000 714 666 666 666 666 285 285 285 285 714 714 785 785 785 785 785 595 785 714 714 714 714 666 666 619 547 547 547 547 547 547 880 500 547 547 547 547 285 285 285 285 547 547 547 547 547 547 547 547 619 547 547 547 547 500 547 500 ] /Encoding /WinAnsiEncoding /FontDescriptor 69 0 R >> endobj 69 0 obj << /Type /FontDescriptor /FontName /Arial /Flags 32 /FontBBox [ -250 -212 1229 1055 ] /MissingWidth 286 /StemV 80 /StemH 80 /ItalicAngle 0 /CapHeight 905 /XHeight 453 /Ascent 905 /Descent -212 /Leading 150 /MaxWidth 1024 /AvgWidth 441 >> endobj 70 0 obj << /Type /Font /Subtype /TrueType /Name /F1 /BaseFont /Arial,Bold /FirstChar 32 /LastChar 255 /Widths [ 285 333 476 547 547 833 714 238 333 333 380 595 285 333 285 285 547 547 547 547 547 547 547 547 547 547 333 333 595 595 595 619 976 690 714 714 714 666 619 785 714 285 547 714 619 833 714 785 666 785 714 666 642 714 666 928 666 666 619 333 285 333 595 547 333 547 619 547 619 547 333 619 619 285 285 547 285 880 619 619 619 619 380 547 333 619 547 785 547 547 500 380 285 380 595 761 761 761 595 595 595 595 595 595 595 595 595 595 595 761 761 761 761 595 595 595 595 595 595 595 595 595 595 595 595 761 761 595 285 333 547 547 547 547 285 547 333 738 380 547 595 333 738 547 404 547 333 333 333 571 547 285 333 333 357 547 833 833 833 619 690 690 690 690 690 690 1000 714 666 666 666 666 285 285 285 285 714 714 785 785 785 785 785 595 785 714 714 714 714 666 666 619 547 547 547 547 547 547 880 547 547 547 547 547 285 285 285 285 619 619 619 619 619 619 619 547 619 619 619 619 619 547 619 547 ] /Encoding /WinAnsiEncoding /FontDescriptor 67 0 R >> endobj 71 0 obj << /Filter /FlateDecode /Length 72 0 R >> stream